Highly selective cobalt-catalyzed hydrovinylation of styrene
Highly selective cobalt-catalyzed hydrovinylation of styrene
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DOI：
10.1021/ja058095y
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发表时间：
2006-06-14
影响因子：
15
通讯作者：
Vogt, Dieter
中科院分区：
文献类型：
--
作者：
Grutters, Michiel M. P.;Muller, Christian;Vogt, Dieter
加氢乙烯化反应是1,3-二烯或乙烯烯与乙烯的共二聚反应，在精细化学品和药品方面具有很大的潜力。首次用含手性膦酰胺配体的钴基体系实现了苯乙烯的对映选择性加氢乙烯化反应。
The hydrovinylation reaction is a codimerization of a 1,3-diene or vinyl arene and ethene with great potential for fine chemicals and pharmaceuticals. For the first time, enantioselective cobalt-catalyzed hydrovinylations of styrene were achieved with a cobalt-based system bearing a chiral bis(phosphine)amide ligand.