Effects of Alkylamines on the Percolation Phenomena in Water/AOT/Isooctane Microemulsions.
Effects of Alkylamines on the Percolation Phenomena in Water/AOT/Isooctane Microemulsions.
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DOI：
10.1006/jcis.2000.6771
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发表时间：
2000-05
影响因子：
9.9
通讯作者：
L. García‐Río;P. Hervés;J. Mejuto;J. Pérez‐Juste;P. Rodríguez-Dafonte
中科院分区：
文献类型：
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作者：
L. García‐Río;P. Hervés;J. Mejuto;J. Pérez‐Juste;P. Rodríguez-Dafonte
我们研究了几种常出现在微乳液反应中的烷基胺对水/AOT/异辛烷体系性能的影响。烷基胺的存在对电渗流现象有重要影响。胺对AOT/异辛烷/水微乳液电渗透的影响可以通过考虑这些底物在微乳液中与AOT膜结合的能力、胺的碱度以及胺在体系三个伪相中的不同溶解度来解释。学术出版社版权所有。
We carried out an investigation on the influence of several alkylamines, frequently present in reactions carried out in microemulsions, on the properties of the water/AOT/isooctane system. The presence of alkylamines has an important effect on the electrical percolation phenomena. This effect of amines on the electrical percolation of microemulsions of AOT/isooctane/water can be explained by taking into account the ability of these substrates to associate with the AOT film in the microemulsion, the basicity of the amine, and the different solubility of the amine in the three pseudophases of the system. Copyright 2000 Academic Press.