Recent Advances in Homogeneous Catalysts for Hydrogen Production from Formic Acid and Methanol
Recent Advances in Homogeneous Catalysts for Hydrogen Production from Formic Acid and Methanol
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DOI：
10.1002/9783527824113.ch10
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发表时间：
2021-03
期刊：
影响因子：
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通讯作者：
Naoya Onishi;Y. Himeda
中科院分区：
文献类型：
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作者：
Naoya Onishi;Y. Himeda
扩大二氧化碳的利用以减少其排放是一个紧迫的问题。因此，利用二氧化碳作为化学反应的原料是非常有吸引力的。近年来，将CO2+ h2o2转化为甲酸、甲醇等C1类化合物的催化剂的开发得到了积极的研究。此外，在不久的将来，氢有望成为主要的能源载体。然而，所谓的向氢经济的转变目前缺乏以安全方式储存氢的能力。因此，由co2加氢产生的甲酸和甲醇作为储氢系统再次受到关注。本章介绍了这些液相储氢材料催化制氢的研究进展。
Expanding the utilization of CO2to reduce its emission is an urgent issue. Therefore, it is very attractive to utilize CO2as a raw material for chemical reactions. Recently, the development of catalysts that convert CO2+ H2into C1 compounds, such as formic acid and methanol, has been actively researched. Moreover, hydrogen is expected to become a major energy carrier in the relatively near future. However, the so‐called shift to a hydrogen economy currently lacks the ability to store hydrogen in a safe manner. Therefore, formic acid and methanol produced from CO2hydrogenation have received renewed attention as a hydrogen storage system. This chapter presents the research progress in catalytic hydrogen generation from these liquid‐phase hydrogen storage materials.