Studies on the Oxide‐Coated Metal Anodes for Chlor‐Alkali Cells
Studies on the Oxide‐Coated Metal Anodes for Chlor‐Alkali Cells
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氯碱电池氧化物涂层金属阳极的研究
DOI：
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发表时间：
1977
期刊：
影响因子：
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通讯作者：
T. Yoshida
中科院分区：
文献类型：
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作者：
F. Hine;M. Yasuda;T. Yoshida
通过DTA/TGA技术和X射线衍射研究了由和组成的混合氧化物的形成。含有钛酸四正丁酯的涂层剂在Ti基底上在约400°C下转化为混合氧化物，并且反应是放热的。通过氧化膜的电阻很大程度上取决于燃烧温度，最佳条件出现在450° C和500°C之间。溶液组成和制备时间也是重要因素。溶液中的阳极极化行为也受到氧化物涂层钛电极的材料或制备条件的影响。
Formation of the mixed oxide consisting of and was studied by the DTA/TGA technique and x‐ray diffraction. The coating agent containing and tetra‐n‐butyl titanate converted into the mixed oxide of and at about 400°C on the Ti substrate, and the reaction was exothermic. The electric resistance through the oxide film depends much on the fire temperature, and an optimum condition arises between 450° and 500°C. The solution composition and the time of preparation are also important factors. The anodic polarization behavior in the solution was also affected by the material or the condition of preparation of the oxide‐coated Ti electrode.