Resonances in the photolysis of HCl in Ar-CHl: Imaging of a resonance wave function in the photofragment angular distribution.
Resonances in the photolysis of HCl in Ar-CHl: Imaging of a resonance wave function in the photofragment angular distribution.
复制标题
Ar-CHl 中 HCl 光解的共振：光碎片角分布中共振波函数的成像。
DOI：
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发表时间：
1993
影响因子：
8.6
通讯作者：
Valentini
中科院分区：
文献类型：
--
作者：
García;Gerber;Imre;Valentini
本文从理论上研究了Ar-HCl团簇中HCl的光解离，重点研究了H原子光解离碎片的角分布。激发态共振，其中氢原子在重原子之间的嘎嘎声，有助于这一过程。据发现，激发到共振态，可测量的角分布的氢原子从Ar-HCl团簇在空间中取向提供了一个映射的共振波函数。这预示了在这样的过程中成像共振波函数的可能性
The photodissociation of HCl in the Ar-HCl cluster is studied theoretically, with the focus on the angular distribution of the H atom photofragments. Excited state resonances, in which the H atom rattles between the heavy atoms, contribute to the process. It is found that for excitation into a resonance state, the measurable angular distribution of H atoms from Ar-HCl clusters oriented in space provides a mapping of the resonance wave function. This predicts the possibility of imaging resonance wave functions in such processes