An Effective and Selective Synthesis of Sterically Crowded Benzotrithioles from Benzodithiastannoles via Benzotrithiole 2-Oxides
An Effective and Selective Synthesis of Sterically Crowded Benzotrithioles from Benzodithiastannoles via Benzotrithiole 2-Oxides
复制标题
通过苯并三硫醇 2-氧化物从苯并二硫杂锡烷有效选择性合成空间拥挤的苯并三硫醇
DOI：
10.1246/cl.1994.507
复制
发表时间：
1994
影响因子：
1.6
通讯作者：
R. Sato
中科院分区：
文献类型：
--
作者：
S. Ogawa;Naoki Yomoji;S. Chida;R. Sato
用亚硫酰氯处理苯二硫醇的合成等效物苯二硫醇，得到相应的苯并三硫醇2-氧化物，通过还原得到立体拥挤的苯并三硫醇，有效地、选择性地制备了苯并三硫醇。
Sterically crowded benzotrithioles were efficiently and selectively prepared by the reduction of corresponding benzotrithiole 2-oxides which were readily obtained on treatment of benzodithiastannoles, synthetic equivalents of benzenedithiols, with thionyl chloride.