A New Class of C2-Symmetric Chiral Cp Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application.
A New Class of C2-Symmetric Chiral Cp Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application.
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DOI：
10.1002/chem.202001814
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发表时间：
2020-05
期刊：
影响因子：
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通讯作者：
Hao-Ran Liang;Laxmaiah Vasamsetty;Teng Li;Jijun Jiang;Xingying Pang;Jun Wang
中科院分区：
文献类型：
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作者：
Hao-Ran Liang;Laxmaiah Vasamsetty;Teng Li;Jijun Jiang;Xingying Pang;Jun Wang
以平面手性二茂铁为骨架，合成了一类新的C2对称手性二茂铁配体.并制备了一系列相应的铑（I）、铱（I）和钌（II）配合物。此外，铑（I）配合物被评估在不对称催化分子内酰胺芳基化烯烃栓苯甲酰胺通过C-H活化。
A new class of C 2 -symmetric, chiral cyclopentadienyl ligand based on planar chiral ferrocene backbone was developed. A series of its corresponding rhodium(I), iridium(I), and ruthenium(II) complexes were prepared as well. In addition, the rhodium(I) complexes were evaluated in the asymmetric catalytic intramolecular amidoarylation of olefin-tethered benzamides via C-H activation.