Contrasting behaviour of related palladium complex-derived resolving agents. 8-H conformational locking of the 1-naphthyl side-chain
Contrasting behaviour of related palladium complex-derived resolving agents. 8-H conformational locking of the 1-naphthyl side-chain
复制标题
相关钯络合物衍生拆分剂的对比行为。
DOI：
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发表时间：
1995
期刊：
影响因子：
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通讯作者：
John M. Brown
中科院分区：
文献类型：
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作者：
N. Alcock;D. I. Hulmes;John M. Brown
本文报道了（R）-N，N-二甲基-1-（1-萘基）乙胺和（S）-N，N-二甲基-1-苯乙胺的钯配合物4和6的X-射线晶体结构。在后者的情况下，两种非对映异构体在配体构型和C，N-螯合环构象上都不同，它们共结晶为准消旋体。
The X-ray crystal structures of palladium complexes 4 and 6 derived from (R)-N,N-dimethyl-1-(1-naphthyl)ethylamine and (S)-N,N-dimethyl-1-phenylethylamine, respectively, are reported; in the latter case two diastereoisomers differing both in the ligand configuration and the conformation of the C,N-chelate ring cocrystallise as a quasiracemate.