Luminescent Anionic Metal-Organic Framework with Potential Nitrobenzene Sensing
Luminescent Anionic Metal-Organic Framework with Potential Nitrobenzene Sensing
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具有潜在硝基苯传感功能的发光阴离子金属有机框架
DOI：
10.1021/cg5004353
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发表时间：
2014-07-01
影响因子：
3.8
通讯作者：
Ma, Jian-Fang
中科院分区：
文献类型：
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作者：
He, Yuan-Chun;Zhang, Hong-Mei;Ma, Jian-Fang
多齿有机配体5,5',5 '',5 '',5],5]'-[1,2,3,4,5,6-苯基六甲氧基]-己二苯二甲酸（H12L）与Cd（NO3）中心点4H(2)O的溶剂热反应生成阴离子三维金属-有机骨架[(CH3)(2)NH2](4)[Cd-3(H2L)](1)，具有新型笼对笼连接的特点。有趣的是，由笼子堆叠的一维通道被分子尺度的砖块分成均匀的片段。对化合物1的发光特性进行了研究，表明化合物1是一种潜在的硝基苯发光传感材料。
Solvothermal reaction of multidentate organic ligand, 5,5',5 '',5 ''',5],5]'-[1,2,3,4,5,6-phenylhexamethoxyl]-hexaisophthalic acid (H12L), with Cd(NO3)center dot 4H(2)O produced an anionic 3D metal-organic framework [(CH3)(2)NH2](4)[Cd-3(H2L)] (1), which features a novel cage-to-cage connection. Interestingly, the 1D channel, which is stacked by cages, is divided into uniform segments by molecular-scale bricks. The luminescent properties of compound 1 have been explored, which shows that 1 is a potential luminescent sensory material for nitrobenzene.