Preparation of an organophilic palladium montmorillonite catalyst in a micellar system
Preparation of an organophilic palladium montmorillonite catalyst in a micellar system
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DOI：
10.1039/a905321b
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发表时间：
1999
影响因子：
4.9
通讯作者：
Z. Kiraly;Bernadett Veisz;I. Dékány;Á. Mastalir;Z. Razga
中科院分区：
文献类型：
--
作者：
Z. Kiraly;Bernadett Veisz;I. Dékány;Á. Mastalir;Z. Razga
蒙脱石钠和作为钯水溶胶稳定剂的十四烷基三甲基溴化铵之间的阳离子交换反应导致形成烷基铵蒙脱石，同时将钯纳米颗粒固定在有机粘土主体中； Pd-有机粘土被证明在液相烯烃加氢中具有催化活性。
The cation-exchange reaction between sodium montmorillonite and tetradecyltrimethylammonium bromide serving as a stabilizing agent in a palladium hydrosol led to the formation of alkylammonium montmorillonite with simultaneous immobilization of the palladium nanoparticles in the organoclay host; the Pd-organoclay proved to be catalytically active in olefin hydrogenation in the liquid phase.