Preparation of AuPt Alloy Foam Films and Their Superior Electrocatalytic Activity for the Oxidation of Formic Acid

Preparation of AuPt Alloy Foam Films and Their Superior Electrocatalytic Activity for the Oxidation of Formic Acid
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AuPt合金泡沫薄膜的制备及其对甲酸氧化的优异电催化活性

DOI:
10.1021/am200782x
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发表时间:
2011-09-01
影响因子:
9.5
通讯作者:
Li, Zelin
Li, Zelin
中科院分区:
材料科学2区
文献类型:
--
作者:
Liu, Jun;Cao, Ling;Li, Zelin

文献摘要

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AuPt alloy films with three-dimensional (3D) hierarchical pores consisting of interconnected dendrite walls were successfully fabricated by a strategy of cathodic codeposition utilizing the hydrogen bubble dynamic template. The foam films were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Due to the special porous structure, the electronic property, and the assembly effect, the AuPt alloy foam films show superior electrocatalytic activity toward the electrooxidation of formic acid in acidic solution, and the prepared 3D porous AuPt alloy films also show high activity and long stability for the electrocatalytic oxidation of methanol, where synergistic effect plays an important role in addition to the electronic effect and assembly effect. These findings provide more insights into the AuPt bimetallic nanomaterials for electrocatalytic applications.