The magnesium(II)-catalyzed asymmetric ketone-ene reaction under solvent-free conditions: stereocontrolled access to enantioenriched trifluoromethyl-substituted compounds.
The magnesium(II)-catalyzed asymmetric ketone-ene reaction under solvent-free conditions: stereocontrolled access to enantioenriched trifluoromethyl-substituted compounds.
复制标题
DOI：
10.1002/chem.201001412
复制
发表时间：
2010-09
期刊：
影响因子：
--
通讯作者：
K. Zheng;Yang Yang-Yang;Jiannan Zhao;C. Yin;Lili Lin;Xiaohua Liu;Xiaoming Feng
中科院分区：
文献类型：
--
作者：
K. Zheng;Yang Yang-Yang;Jiannan Zhao;C. Yin;Lili Lin;Xiaohua Liu;Xiaoming Feng
三氟丙酮酸的不对称酮-烯反应由手性 Mg(OTf)2-N,N'-二氧化物络合物有效催化。
The asymmetric ketone—ene reaction of trifluoropyruvate is efficiently catalyzed by a chiral Mg(OTf)2—N,N′-dioxide complex.