REARRANGEMENT OF ALLYL ETHERS TO PROPENYL ETHERS
REARRANGEMENT OF ALLYL ETHERS TO PROPENYL ETHERS
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DOI：
10.1021/ja01468a035
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发表时间：
1961-01-01
影响因子：
15
通讯作者：
PROSSER, TJ
中科院分区：
文献类型：
--
作者：
PROSSER, TJ
几个单官能团烯丙基醚和多官能团烯丙基醚在碱性催化剂存在下，在150-175℃下重排成相应的丙烯基醚。重排反应是立体选择性的，产物为95-100%的顺丙烯基醚。催化剂失活效应与催化剂初始浓度有关，而不是温度的函数。重排反应为丙烯基醚的制备提供了一种方便的方法。
Several mono- and polyfunctional allyl ethers have been rearranged to the corresponding propenyl ethers by treatment at 150-175 in the presence of a basic catalyst. The rearrangement reaction is stereospecific, yielding 95-100% cis-propenyl ether, A catalyst deactivation effect is observed with ultimate degree of rearrangement being a function of initial catalyst concentration but not of temperature. The rearrangement reaction affords a convenient preparative procedure for propenyl ethers.