Polysiloxane-supported NAD(P)H model 1-benzyl-1,4-dihydronicotinamide: synthesis and application in the reduction of activated olefins.
Polysiloxane-supported NAD(P)H model 1-benzyl-1,4-dihydronicotinamide: synthesis and application in the reduction of activated olefins.
复制标题
DOI:
10.1021/jo020319x
复制
发表时间:
2003-03
期刊:
影响因子:
--
通讯作者:
Baolian Zhang;Xiao‐Qing Zhu;Jin-Yong Lu;Jiaqi He;P. Wang;Jin‐Pei Cheng
中科院分区:
文献类型:
--
作者:
Baolian Zhang;Xiao‐Qing Zhu;Jin-Yong Lu;Jiaqi He;P. Wang;Jin‐Pei Cheng
A new polysiloxane-supported NAD(P)H model, 1-benzyl-1,4-dihydronicotinamide, was designed and synthesized, which can efficiently reduce many activated olefins under mild conditions. The most advantageous features of this new polysiloxane-supported reductant are (i) easy workup and separation of the reaction products and (ii) good potential for recycling use of the reductant, which makes this new polysiloxane-supported NAD(P)H model a promising alternative both in research laboratories and in industrial processes.