Fascinating reactivity in gold catalysis: synthesis of oxetenes through rare 4-exo-dig allene cyclization and infrequent β-hydride elimination

Fascinating reactivity in gold catalysis: synthesis of oxetenes through rare 4-exo-dig allene cyclization and infrequent β-hydride elimination
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DOI:
10.1039/c1cc13212a
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Fernandez, Israel
Fernandez, Israel
中科院分区:
化学2区
文献类型:
--
作者:
Alcaide, Benito;Almendros, Pedro;Fernandez, Israel

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A novel reactivity in gold catalysis, namely the unusual preference for the 4-exo-dig cyclization in allene chemistry as well as the rare beta-hydride elimination reaction, was uncovered starting from readily available allenols.