Bifunctional microstructured films and surfaces obtained by soft lithography from breath figure arrays

Bifunctional microstructured films and surfaces obtained by soft lithography from breath figure arrays
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DOI:
10.1039/b819811j
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发表时间:
2009-04
期刊:
影响因子:
3.4
通讯作者:
Varun Vohra;S. Yunus;Anne Attout;U. Giovanella;G. Scavia;R. Tubino;C. Botta;A. Bolognesi
Varun Vohra;S. Yunus;Anne Attout;U. Giovanella;G. Scavia;R. Tubino;C. Botta;A. Bolognesi
中科院分区:
化学2区
文献类型:
--
作者:
Varun Vohra;S. Yunus;Anne Attout;U. Giovanella;G. Scavia;R. Tubino;C. Botta;A. Bolognesi

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使用具有600 nm和5 µm规则图案的聚苯乙烯和聚烷基噻吩的呼吸图形膜作为模板,制备含有截留量的初级聚合物的负性聚二甲基硅氧烷印模。这些呼吸图复制品用于在任何基底上以网络形式产生单层或双层的截留的共轭聚合物。除此之外,以这种方式印刷的聚苯乙烯可以用作抗蚀剂掩模,其允许苯胺在铂电极上以规则的微米排列聚合,或者在普通聚苯胺膜上产生规则的酸/碱图案化。
Breath figure films of polystyrene and polyalkylthiophene presenting regular patterns of 600 nm and 5 µm are used as templates to prepare negative polydimethylsiloxane stamps containing an entrapped quantity of the primary polymer. These breath figure replica are used to generate single or double layers of the entrapped conjugated polymer in the form of networks on any substrates. Besides this, polystyrene printed in this way can be used as a resist mask that allows the polymerization of aniline in a regular micrometric arrangement on a platinum electrode or to generate a regular acid/base patterning on a plain polyaniline film.