Trigonal-bipyramidal geometry in a Cobalt(II) complex with an unsymmetrical tripodal ligand

Trigonal-bipyramidal geometry in a Cobalt(II) complex with an unsymmetrical tripodal ligand
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具有不对称三足配体的钴(II)配合物中的三角双锥几何形状

DOI:
10.1246/bcsj.74.2131
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发表时间:
2001
期刊:
影响因子:
--
通讯作者:
H. Sakiyama
H. Sakiyama
中科院分区:
--
文献类型:
--
作者:
Jong;M. Mikuriya;H. Sakiyama

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合成了双[2-(3,5-二甲基吡唑-1-基)乙基][(吡唑-1-基)甲基]胺(bppa)[CoCl(bppa)][B(C6H5)4]·C2H5OH的钴(II)配合物,并通过磁矩和电子光谱测量对其进行了表征。 X射线晶体结构表明该化合物具有扭曲的三角双锥体,配位环境为N4Cl。
A cobalt(II) complex with bis[2-(3,5-dimethylpyrazol-1-yl)ethyl][(pyrazol-1-yl)methyl]amine (bppa), [CoCl(bppa)][B(C6H5)4]·C2H5OH, was synthesized and characterized by measurements of the magnetic moment and the electronic spectra. The X-ray crystal structure shows that the compound has a distorted trigonal bipyramid with a N4Cl coordination environment.