Palladium-catalyzed carbon-nitrogen bond formation:: A novel, catalytic approach towards N-arylated sulfoximines

Palladium-catalyzed carbon-nitrogen bond formation:: A novel, catalytic approach towards N-arylated sulfoximines
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DOI:
10.1016/s0040-4039(98)01199-x
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发表时间:
1998-08-06
影响因子:
1.8
通讯作者:
Hildebrand, JP
Hildebrand, JP
中科院分区:
化学4区
文献类型:
--
作者:
Bolm, C;Hildebrand, JP

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在Pd(OAc)(2)的催化量和螯合双膦的存在下,亚砜亚胺1与不同取代模式的芳基溴偶联得到n -芳基化产物3,产率高达96%。1998爱思唯尔科学有限公司版权所有。
The coupling of sulfoximines 1 with various aryl bromides of different substitution pattern in the presence of a catalytic amount of Pd(OAc)(2) and a chelating bisphosphine affords N-arylated products 3 with yields of up to 96%. (C) 1998 Elsevier Science Ltd. All rights reserved.