Porous Lanthanide Metal–Organic Frameworks for Gas Storage and Separation
Porous Lanthanide Metal–Organic Frameworks for Gas Storage and Separation
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DOI：
10.1007/430_2014_159
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发表时间：
2014
影响因子：
--
通讯作者：
Bin Li;Banglin Chen
中科院分区：
文献类型：
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作者：
Bin Li;Banglin Chen
镧系金属有机骨架（Ln-MOFs）由于其高孔隙率、可调节的孔径/尖锐度、容易的功能化以及高的热/化学稳定性，在过去的几十年中作为一种新兴类型的多孔材料引起了越来越多的关注。在这一章中，我们不仅试图提供一个全面的审查重点放在多孔Ln-MOF材料的广泛的应用在气体存储和分离，如H2存储，选择性CO2捕获和分离，以及H2和CH 4的净化，但也强调了一些策略，作为一种手段，有效地提高其气体存储容量和选择性。
Lanthanide metal–organic frameworks (Ln-MOFs) have attracted increasing attention as an emerging type of porous materials in the last decades due to their high porosities, adjustable pore sizes/sharps, ready functionalization, as well as high thermal/chemical stability. In this chapter, we seek to not only provide a comprehensive review focusing on porous Ln-MOF materials for a wide range of applications in gas storage and separation, such as H2storage, selective CO2capture and separation, and H2and CH4purification, but also highlight some strategies as a means of effectively enhancing their gas storage capacities and selectivities.