Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid

Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid
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N80碳钢在含乙酸CO2饱和环境中的缝隙腐蚀

DOI:
10.1016/j.corsci.2016.08.002
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发表时间:
2016-11
期刊:
影响因子:
8.3
通讯作者:
Zhang G. A.
Zhang G. A.
中科院分区:
材料科学1区
文献类型:
--
作者:
Li Y. Z.;Xu N.;Liu G. R.;Guo X. P.;Zhang G. A.

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通过电化学测试和表面分析,研究了N80碳钢在含醋酸的CO2饱和环境中的缝隙腐蚀行为。缝隙外半电极无明显腐蚀,缝隙内半电极腐蚀严重,缝隙口出现深腐蚀凹槽。碳钢的缝隙腐蚀是由缝隙内外两个半电极之间的电偶效应引起的。随着HAc浓度的增加,缝隙内、外两个半电极之间的电偶效应增强,从而促进缝隙腐蚀。
Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid (HAc) was studied by electrochemical measurements and surface analysis. No obvious corrosion is observed on the half-electrode outside crevice while severe corrosion occurs on the half-electrode inside crevice, and deep corrosion groove appears at the crevice mouth. Crevice corrosion of carbon steel is triggered by the galvanic effect between the two half-electrodes inside and outside crevice. Crevice corrosion is promoted by increasing the HAc concentration because the galvanic effect between the two half-electrodes inside and outside crevice is strengthened with the increase of HAc concentration.
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