Electron collisions with nitrous oxide

Electron collisions with nitrous oxide
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电子与一氧化二氮的碰撞

DOI:
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发表时间:
1998
期刊:
影响因子:
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通讯作者:
V. McKoy
V. McKoy
中科院分区:
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文献类型:
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作者:
C. Winstead;V. McKoy

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我们已经进行了低能弹性电子与一氧化二氮(N2 O)碰撞的理论研究,获得微分,积分和动量转移截面。极化效应被纳入电子-分子散射动力学。一个简单的,客观的,和物理动机的标准被引入构造一组紧凑的配置,准确地占在共振对称性的极化,同时避免过相关。我们的横截面与实验和早期的高级计算基本一致,大多数差异都很容易理解。然而,计算和测量的微分截面之间的某些差异仍然令人困惑。
We have carried out theoretical studies of low-energy elastic electron collisions with nitrous oxide (N2O), obtaining differential, integral, and momentum-transfer cross sections. Polarization effects are incorporated in the electron-molecule scattering dynamics. A simple, objective, and physically motivated criterion is introduced for constructing a compact set of configurations that accurately accounts for polarization in resonant symmetries while avoiding overcorrelation. Our cross sections are in generally good agreement with experiment and with earlier high-level calculations, and most differences are readily understood. However, certain discrepancies between the calculated and measured differential cross sections remain puzzling.