p- and n-Type Bipolar Redox-Active Radical Polymer: Toward Totally Organic Polymer-Based Rechargeable Devices with Variable Configuration
p- and n-Type Bipolar Redox-Active Radical Polymer: Toward Totally Organic Polymer-Based Rechargeable Devices with Variable Configuration
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DOI：
10.1002/adma.201003525
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发表时间：
2011-02-08
影响因子：
29.4
通讯作者：
Nishide, Hiroyuki
中科院分区：
文献类型：
--
作者：
Suga, Takeo;Sugita, Shuhei;Nishide, Hiroyuki
带有硝基硝基的p-型和n型双极氧化还原活性自由基聚合物聚(硝基-硝基-苯乙烯)，通过两种前所未有的配置：无极电池和摇椅式电池，扩大了其作为阴极或阳极活性材料在基于有机聚合物的充电设备中的应用。这些电池表现出非常高的功率比能力(可在20 S内充电)和高循环性能。
The p- and n-type bipolar redox-active radical polymer with a nitronylnitroxyl group, poly(nitronylnitroxylstyrene), expands its utilization as a cathode-or anode-active material in organic polymer-based rechargeable devices with two unprecedented configurations: a poleless battery and a "rocking-chair type" battery. These batteries exhibit a remarkably high power rate capability (chargeable within 20 s) and high cycle performance.[GRAPHICS].