Direct observation of the reversible redox couple trisilver(2+) (Ag32+) .dblarw. trisilver (Ag30) in silver zeolite A by Fourier transform far-infrared - infrared spectroscopy

Direct observation of the reversible redox couple trisilver(2+) (Ag32+) .dblarw. trisilver (Ag30) in silver zeolite A by Fourier transform far-infrared - infrared spectroscopy
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可逆氧化还原对三银(2) (Ag32) 的直接观察.dblarw。

DOI:
10.1021/j150665a020
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发表时间:
1984
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
J. Godber
J. Godber
中科院分区:
--
文献类型:
--
作者:
M. Baker;G. Ozin;J. Godber

文献摘要

被引文献

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第一次研究选择的三银系统是由大量化学和动力学,6,7光谱的可用性预测的。(光学,EPR),8 9 X射线衍射,5,8,9以及电子和磁学理论10 * 的Ag 3g +(其中q = 0,1,2)孤立在支持范围从固体稀有气体11和(1)(a)"双原子金属和金属簇";法拉第Symp.化学会,14,7,(1980)。(b)"金属簇的生长和性质;阳离子催化和照相过程",第32届化学学会国际会议论文集,J. Bourdon编辑,爱思唯尔,纽约,1980年。(c)"第二届小颗粒和无机团簇国际会议论文集",洛桑,瑞士,1980年。冲浪。科学,106,1,(1981),以及其中引用的参考文献。(2)(a)W. H.萨赫特勒角Backx和R. a.货车Santen,Cat. Rev.工程师:23,127(1981);(B)E. L. Force和AT Bell,J.Catal.,40,356(1975); 38,440(1975); 44,175(1976),以及其中引用的参考文献。(3)(a)S. Leutwyler和E. Schumacher,Chimia,31,475(1977);(B)P. A.雅各布斯,JB Uytterhoeven,和。K. Beyer,J. Chem. Soc.,化学通信,128(1977)。
The choice of the trisilver system for this first study was predicated by the availabilityof a substantial body of chemical and kinetic, 6, 7 spectroscopic (optical, EPR), 8 9X-ray diffraction, 5, 8, 9 as well as electronic and magnetic theory10* for Ag3g+(where q= 0, 1, 2) isolated in supports ranging from solid rare gases11 and (1)(a)“Diatomic Metals and Metal Clusters”; Faraday Symp. Chem. Soc., 14, 7,(1980).(b)“Growth and Properties of Metal Clusters; Appli-cations to Catalysis and the Photographic Process”, Proceeding of the 32nd International Meeting of Societyde Chemical, J. Bourdon, Ed., Elsevier, New York, 1980.(c)“Proceedings of the Second International Meeting on Small Particles and Inorganic Clusters”, Lausanne, Switzerland, 1980. Surf. Sci., 106, 1,(1981), and references cited threin.(2)(a) W.. H. Sachtler, C. Backx, and R. A. van Santen, Cat. Rev. Sci. Eng., 23, 127 (1981);(b) E. L. Force and AT Bell, J. Catal., 40, 356 (1975); 38, 440 (1975); 44,175 (1976), and references cited therein.(3)(a) S. Leutwyler and E. Schumacher, Chimia, 31, 475 (1977);(b) P. A. Jacobs, JB Uytterhoeven, and. K. Beyer, J. Chem. Soc., Chem. Commun., 128 (1977).