Coherent control of chirality in ensemble of randomly oriented molecules using a sequence of short laser pulses
Coherent control of chirality in ensemble of randomly oriented molecules using a sequence of short laser pulses
复制标题
使用一系列短激光脉冲对随机定向分子集合中的手性进行相干控制
DOI：
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发表时间：
2010
期刊：
影响因子：
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通讯作者：
V. Zadkov
中科院分区：
文献类型：
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作者：
D. V. Zhdanov;V. Zadkov
提出了一种选择短激光脉冲序列的通用算法，该序列可以选择性地激发旋转冷分子的外消旋混合物中的特定对映体。以激光控制过氧化氢分子混合物中不同手性构象的含量为例说明了其应用。本文还讨论了在动态手性情况下检测外消旋体断裂的方法。
The universal algorithm of choosing the train of short laser pulses, which could selectively excite the specific enantiomers in a racemic mixture of rotationally cold molecules, is proposed. Its application is illustrated on example of laser control of content of different chiral conformations in the mixture of hydrogen peroxide molecules. Methods of detection of racemity breaking in case of dynamical chirality are also discussed.