Reactions of triazines and tetrazines with dienophiles (Review)
Reactions of triazines and tetrazines with dienophiles (Review)
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DOI：
10.1007/s10593-012-1117-9
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发表时间：
2012-11-01
影响因子：
1.5
通讯作者：
Kozhevnikov, D. N.
中科院分区：
文献类型：
--
作者：
Prokhorov, A. M.;Kozhevnikov, D. N.
综述了近年来基于反电子需求Diels-Alder反应合成缺π氮杂二烯（三嗪和四嗪）系列化合物的研究进展。通过该方法，可以从初始吖嗪和亲二烯体两者获得含有官能取代基的单、二和三嗪。这种反应通常是合成具有适合实际应用的性质的物质的最简单甚至是唯一可能的方法。
Information on the development of a valuable synthetic methodology based on inverse electron-demand Diels-Alder reaction in the series of pi-deficient azadienes (triazines and tetrazines) is summarized and classified. By this method it is possible to obtain mono-, di-, and triazines containing functional substituents both from the initial azine and from the dienophile. Such reactions are often the simplest and even the only possible method for the synthesis of substances with properties suitable for practical applications.