STOICHIOMETRY OF REACTION BETWEEN METHYLMERCURY(II) IODIDE AND SOLUBLE SULPHIDES
STOICHIOMETRY OF REACTION BETWEEN METHYLMERCURY(II) IODIDE AND SOLUBLE SULPHIDES
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DOI：
10.1016/0003-2670(70)80069-1
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发表时间：
1970-01-01
影响因子：
6.2
通讯作者：
GRUEN, LC
中科院分区：
文献类型：
--
作者：
GRUEN, LC
对于碘化甲基汞（II）和硫化钠之间的特定反应，在20°和pH 9.2的电流滴定中观察到严格的2：1化学计量比。该化学计量适用于高达至少pH 12.7和宽范围的试剂浓度。反应发生迅速，所涉及的两个步骤似乎都不是限速的。
For the specific reaction between methylmercury(II) iodide and sodium sulphide, a strict 2:1 stoichiometry was observed in amperometric titrations at 20° and at pH 9.2. This stoichiometry applies up to at least pH 12.7 and to wide ranges of reagent concentrations. The reaction occurs rapidly and neither of the two steps involved appears to be rate-limiting.