Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by 13C DQ solid-state NMR spectroscopy.
Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by 13C DQ solid-state NMR spectroscopy.
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DOI：
10.1039/c2cc37384j
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发表时间：
2013-01
影响因子：
4.9
通讯作者：
Marko Schmidt;J. J. Wittmann-J.;R. Kress;H. Schmidt;J. Senker
中科院分区：
文献类型：
--
作者：
Marko Schmidt;J. J. Wittmann-J.;R. Kress;H. Schmidt;J. Senker
使用（13）C双量子固体核磁共振波谱，我们能够在浓度仅为0.09 wt%的i-PP基质中观察到纳米尺度上基于BTA的超分子添加剂的核。这些核表现出与纯添加剂的结晶相类似的结构特征。
Using (13)C double quantum solid-state NMR spectroscopy, we were able to observe nuclei of a supramolecular BTA based additive on the nanoscale in a matrix of i-PP at a concentration of only 0.09 wt%. These nuclei exhibit the analogous structural features as the crystalline phase of the neat additive.