Formation of the intermediate-spin iron(III) porphyrin complexes with (dxz, dyz)3(dxy)1(dz2)1 electron configuration.
Formation of the intermediate-spin iron(III) porphyrin complexes with (dxz, dyz)3(dxy)1(dz2)1 electron configuration.
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DOI：
10.1021/ja030448a
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发表时间：
2003-10
影响因子：
15
通讯作者：
T. Sakai;Y. Ohgo;T. Ikeue;Masashi Takahashi;M. Takeda;Mikio Nakamura
中科院分区：
文献类型：
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作者：
T. Sakai;Y. Ohgo;T. Ikeue;Masashi Takahashi;M. Takeda;Mikio Nakamura
根据介观13C化学位移的差异，我们得出结论，具有高褶皱和高鞍状卟啉的中间自旋铁(III)配合物具有不同的电子构型。后者采用传统的 (dxy)2(dxz, dyz)2(dz2)1，而前者采用新颖的 (dxz, dyz)3(dxy)1(dz2)1。
On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1.