First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [(Cu(1,2-pn)2)7(V16O38(H2O))2].4H2O.
First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [(Cu(1,2-pn)2)7(V16O38(H2O))2].4H2O.
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DOI：
10.1039/b206880j
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发表时间：
2002-09
影响因子：
4.9
通讯作者：
B. Lin;Shi-xiong Liu
中科院分区：
文献类型：
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作者：
B. Lin;Shi-xiong Liu
以V2 O 5、Cu（CH 3COO）2·H2O、1，2-丙二胺和[N（CH 3）4]OH为原料，通过水热反应合成了一种新型的三维开放骨架固体[（Cu（1，2-pn）2）7-（V16 O38（H2O））2]·4 H2O.
The hydrothermal reaction of V2O5, Cu(CH3COO)2.H2O, 1,2-diaminopropane and [N(CH3)4]OH yields the novel three-dimensional open-framework solid [(Cu(1,2-pn)2)7-(V16O38(H2O))2].4H2O constructed from the new mixed-valence [V16O38(H2O)]7- clusters interconnected through mu 2-[Cu(1,2-pn)2]2+ groups.