Formation mechanism of Si-Y-C ceramic matrix by reactive melt infiltration using Si-Y alloy and properties of C/Si-Y-C composites

Formation mechanism of Si-Y-C ceramic matrix by reactive melt infiltration using Si-Y alloy and properties of C/Si-Y-C composites
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Si-Y合金反应熔渗Si-Y-C陶瓷基体形成机理及C/Si-Y-C复合材料性能

DOI:
10.1016/j.ceramint.2020.04.225
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发表时间:
2020-08
影响因子:
5.2
通讯作者:
Hu Rui
Hu Rui
中科院分区:
材料科学1区
文献类型:
--
作者:
Gao Yuqing;Liu Yongsheng;Wang Jing;Zhang Chengyu;Pedzich Zbigniew;Li Jinguang;Hu Rui

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本文采用反应熔渗法(RMI)将Si-Y共晶合金引入多孔C/C预制体中制备C/Si-Y-C复合材料。研究了复合材料的相组成及其分布。结果表明,在Si-Y-C基体的典型区中,存在四个主要区域,非晶碳、掺杂有YSi 2的多晶SiC、非晶SiC和单晶YSi 2。基于Si-Y合金与C/C预制体之间的反应和显微组织观察,提出了一个反映反应过程的显微组织形成机理模型。与C/C-SiC相比,C/Si-Y-C复合材料的抗弯强度、断裂韧性、热扩散率和导热率均有所提高。
Herein, Si-Y eutectic alloy were introduced into porous C/C preform by reactive melt infiltration (RMI) to prepare C/Si-Y-C composite. Phase compositions and their distributions in the as-prepared composites were investigated. Result indicated that four main regions were found in the typical zone in Si-Y-C matrix, i.e., amorphous carbon, polycrystalline SiC doped with YSi2, amorphous SiC and single crystal YSi2. Based on the reaction between Si-Y alloy and C/C preform and microstructural observations, a model regarding to microstructure formation mechanism was proposed to reveal reaction process. Moreover, improved flexural strength, fracture toughness, thermal diffusivity and thermal conductivity of C/Si-Y-C composite were achieved compared to C/C-SiC.
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