A Free Radical Cascade Silylarylation of Activated Alkenes: Highly Selective Activation of the Si-H/C-H Bonds
A Free Radical Cascade Silylarylation of Activated Alkenes: Highly Selective Activation of the Si-H/C-H Bonds
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DOI：
10.1021/acs.orglett.5b01067
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发表时间：
2015-05-15
期刊：
影响因子：
5.2
通讯作者：
Liu, Zhong-Quan
中科院分区：
文献类型：
--
作者：
Zhang, Lizhi;Liu, Dong;Liu, Zhong-Quan
通过Si-H/C-H键的选择性活化报道了活化烯烃与硅烷的甲硅烷基芳基化的第一个实例，这允许通过自由基级联过程有效地获得甲硅烷基化的羟吲哚。
The first example of silylarylation of activated alkenes with silanes is reported via selective activation of the Si-H/C-H bonds, which allows efficient access to silylated oxindoles through a free-radical cascade process.