Electrochemical Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na
Electrochemical Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na
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CF3SO2Na α,β-不饱和羧酸的电化学脱羧三氟甲基化
DOI：
10.1002/cctc.201900438
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发表时间：
2019
期刊：
影响因子：
4.5
通讯作者：
Huang Jing Mei
中科院分区：
文献类型：
--
作者：
Li Fang Yuan;Lin Dian Zhao;He Tian Jun;Zhong Wei Qiang;Huang Jing Mei
提出了以α，β-不饱和羧酸和CF3SO2Na为原料合成乙烯基三氟甲基化合物的新方法。在无金属和无外部化学氧化剂的条件下，这种电化学脱羧基三氟甲基化反应具有高的立体选择性，产物的产率高，底物范围宽。
A new method for the synthesis of vinyl trifluoromethyl compounds fromα, β‐unsaturated carboxylic acids and CF3SO2Na has been developed. This electrochemical decarboxylative trifluoro‐methylation was found to be highly stereoselective and afforded products in good yields with wide substrate scope under metal‐free and external chemical oxidant‐free conditions.