Mono and bis[N-aryl(benzyl)]amides of phosphorylacetic acids. One-pot synthesis and extraction of actinides from nitric acid solutions
Mono and bis[N-aryl(benzyl)]amides of phosphorylacetic acids. One-pot synthesis and extraction of actinides from nitric acid solutions
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磷酸乙酸的单和双[N-芳基（苄基）]酰胺。
DOI：
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发表时间：
2006
期刊：
影响因子：
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通讯作者：
G. V. Myasoedova
中科院分区：
文献类型：
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作者：
O. Artyushin;E. Sharova;I. Odinets;K. Lyssenko;D. G. Golovanov;T. Mastryukova;G. A. Pribylova;I. Tananaev;G. V. Myasoedova
一锅法合成磷酰基乙酸N-芳基（烷芳基）酰胺，包括那些含有两个磷酰基甲基氨基甲酰基部分连接到芳烃框架，已开发。该方法是基于胺与相应的酰氯的反应，使用磷酰氯作为温和的氯化剂原位生成。测定了所得化合物的组成和结构及其对AmIII的萃取能力。对磷酰乙酸N-芳基（烷芳基）酰胺萃取配合物的组成提出了建议。
A one-pot synthetic route to phosphorylacetic acid N-aryl(alkylaryl)amides, including those containing two phosphorylmethylcarbamoyl moieties attached to the arene framework, has been developed. The method is based on reactions of amines with the corresponding acid chlorides generated in situ with the use of phosphorus trichloride as a mild chlorinating agent. The compositions and structures of the compounds obtained and their extraction ability toward AmIII were determined. Suggestions were made about the compositions of the extracted complexes with phosphorylacetic acid N-aryl(alkylaryl)amides.