Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.
Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.
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DOI：
10.1021/acs.chemrev.5b00162
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发表时间：
2015-09-09
期刊：
影响因子：
62.1
通讯作者：
Reisman SE
中科院分区：
文献类型：
--
作者：
Cherney AH;Kadunce NT;Reisman SE
C-C键的立体控制结构仍然是有机合成中最重要的挑战之一。天然产物或设计的小分子的任何化学合成的核心是需要协调一系列化学反应以制备和官能化碳框架。过渡金属催化剂的出现为化学家提供了
The stereocontrolled construction of C− C bonds remains one of the foremost challenges in organic synthesis. At the heart of any chemical synthesis of a natural product or designed small molecule is the need to orchestrate a series of chemical reactions to prepare and functionalize a carbon framework. The advent of transition-metal catalysis has provided chemists with