NaH-mediated direct C-H arylation in the presence of 1,10-phenanthroline
NaH-mediated direct C-H arylation in the presence of 1,10-phenanthroline
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1,10-菲咯啉存在下 NaH 介导的直接 C-H 芳基化
DOI：
10.1039/d0cc00730g
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
and Yoshinori Kondo
中科院分区：
文献类型：
--
作者：
Kanako Nozawa-Kumada;Yuki Iwakawa;So Onuma;Masanori Shigeno;and Yoshinori Kondo
在NaH和1，10-菲咯啉存在下，卤代芳烃与未活化芳烃的无过渡金属偶联已经发展。带有甲基、甲氧基、卤素（氟、氯和溴）、氰基、三氟甲基、酯和酰胺基团的各种卤代芳烃可以在该反应中与未活化的芳烃或杂芳烃交叉偶联。
Transition-metal-free coupling of haloarenes with unactivated arenes has been developed in the presence of NaH and 1,10-phenanthroline. Various haloarenes bearing methyl, methoxy, halogen (fluoride, chloride, and bromide), cyano, trifluoromethyl, ester, and amide groups can be cross-coupled with unactivated arenes, or heteroarenes in this reaction.