A comparative study on Na2MnPO4F and Li2MnPO4F for rechargeable battery cathodes.
A comparative study on Na2MnPO4F and Li2MnPO4F for rechargeable battery cathodes.
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DOI：
10.1039/c2cp40082k
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发表时间：
2012-02
期刊：
影响因子：
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通讯作者：
Sung-Wook Kim;D. Seo;Hyungsub Kim;Kyu‐Young Park;K. Kang
中科院分区：
文献类型：
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作者：
Sung-Wook Kim;D. Seo;Hyungsub Kim;Kyu‐Young Park;K. Kang
用实验和第一性原理计算研究了A（2）MnPO（4）F（A = Na/Li）的电化学性质。首次合成了Li（2）MnPO（4）F新相。在合理的电压窗口内，一个碱金属离子的反应可逆地发生，而在较高的电压下，两个碱金属离子的反应发生。
Electrochemical properties of A(2)MnPO(4)F (A = Na/Li) were investigated both experimentally and with first principles calculations. A new Li(2)MnPO(4)F phase was successfully synthesized for the first time. A one alkali metal ion reaction occurred reversibly within a reasonable voltage window and a two alkali metal ion reaction took place at higher voltages.