Finding a receptor design for selective recognition of perrhenate and pertechnetate: hydrogen vs. halogen bonding.
Finding a receptor design for selective recognition of perrhenate and pertechnetate: hydrogen vs. halogen bonding.
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DOI：
10.1039/c8cc02048e
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发表时间：
2018-05
影响因子：
4.9
通讯作者：
A. Ravi;A. Oshchepkov;K. German;G. A. Kirakosyan;A. V. Safonov;V. Khrustalev;E. Kataev
中科院分区：
文献类型：
--
作者：
A. Ravi;A. Oshchepkov;K. German;G. A. Kirakosyan;A. V. Safonov;V. Khrustalev;E. Kataev
设计并研究了带有氢键和卤键供体的受体对过氧化氢和高锝酸的识别。具有N-H和C-H结合位点的无环主体对TcO 4-和ReO 4-的选择性最好，而不是球形和更碱性的四面体阴离子。
Receptors bearing hydrogen and halogen bond donors for recognition of perrhenate and pertechnetate were designed and studied. Acyclic hosts with N-H and C-H binding sites showed the best selectivity for TcO4- and ReO4- over spherical and more basic tetrahedral anions.