Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor
Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor
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DOI：
10.1021/ja108898t
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发表时间：
2010-12-01
影响因子：
15
通讯作者：
Somorjai, Gabor A.
中科院分区：
文献类型：
--
作者：
Huang, Wenyu;Liu, Jack Hung-Chang;Somorjai, Gabor A.
开发了一种高活性的多相Pd纳米粒子催化剂，用于苯酚与炔烃的分子内加成反应，并将其应用于连续流动反应系统中。以流动模式运行反应揭示了反应动力学，例如活化能和催化剂失活，并且提供了许多潜在的实际优点。
A highly active heterogeneous Pd-nanoparticle catalyst for the intramolecular addition of phenols to alkynes was developed and employed in a continuous flow reaction system. Running the reaction in flow mode revealed reaction kinetics, such as the activation energy and catalyst deactivation, and provides many potential practical advantages.