Recent Advances and Perspectives of Zn‐Metal Free “Rocking‐Chair”‐Type Zn‐Ion Batteries
Recent Advances and Perspectives of Zn‐Metal Free “Rocking‐Chair”‐Type Zn‐Ion Batteries
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DOI：
10.1002/aenm.202002529
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发表时间：
2020-12
影响因子：
27.8
通讯作者：
Yuan Tian;Y. An;Chuanliang Wei;Baojuan Xi;S. Xiong;Jinkui Feng;Yitai Qian
中科院分区：
文献类型：
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作者：
Yuan Tian;Y. An;Chuanliang Wei;Baojuan Xi;S. Xiong;Jinkui Feng;Yitai Qian
在过去的几十年里，世界见证了具有无锂金属阳极的“摇椅”型锂离子电池的成功商业化。由于其安全，绿色，易于制造和成本效益的特性，锌可充电电池最近受到越来越多的关注。然而，锌金属电池的实际应用主要受到锌金属阳极的枝晶生长的阻碍，其导致库仑效率差、危险和各种副反应。在此，新兴的“摇椅”型锌离子电池系统地审查与锌主机阳极，而不是锌金属阳极。作为介绍，讨论了“摇椅”型锌离子电池的基本原理、优点和挑战。随后，总结了“摇椅”锌离子电池的阴极、阳极和电解液的设计原则和最新进展。最后，提出了对“摇椅”锌离子电池未来的展望。希望这篇综述可以为锌离子电池的设计提供替代方向。
In the past decades, the world has witnessed the successful commercialization of “rocking‐chair”‐type lithium‐ion batteries with lithium metal free anodes. Owing to their safe, green, easy manufacturing, and cost‐efficiency characteristics, rechargeable zinc batteries have recently received more and more attention. However, the practical application of Zn metal batteries is hampered mainly by the dendritic growth of Zn metal anode, which leads to poor Coulombic efficiency, hazards, and various side reactions. Herein, the emerging “rocking‐chair”‐type Zn‐ion batteries are systemically reviewed with Zn host anodes instead of Zn metal anodes. As an introduction, the fundamental principles, advantages, and challenges of “rocking‐chair”‐type Zn‐ion batteries are discussed. Subsequently, the design principles and recent advances of cathode, anode, and electrolyte for “rocking‐chair” Zn‐ion batteries are summarized. To conclude, perspectives on the future of “rocking‐chair” Zn‐ion batteries are presented. It is hoped that this review may provide alternative directions for the design of Zn‐ion batteries.