Transformation of propargylic alcohols into enones
Transformation of propargylic alcohols into enones
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DOI：
10.1246/bcsj.65.2594
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发表时间：
1992-10
影响因子：
4
通讯作者：
Y. Shigemasa;H. Oikawa;Shin-ichiro Ohrai;H. Sashiwa;H. Saimoto
中科院分区：
文献类型：
--
作者：
Y. Shigemasa;H. Oikawa;Shin-ichiro Ohrai;H. Sashiwa;H. Saimoto
α,α-Disubstituted propargylic alcohols were transformed into enones by the catalysis with Ag(I) or Ag(I)–Me3SiCl under the mild conditions. This procedure provides a new synthetic method of α,β-unsaturated ketones having an oxygen function at α′ position from 2-butyne-1,4-diol derivatives. 3-Acetoxy-1,4,4-triphenyl-3-buten-2-one was obtained from 4-acetoxy-1,1,4-triphenyl-2-butyn-1-ol by the catalysis with tin(IV) chloride or aluminium chloride.
