Fast Photocurrent Transients in Photoelectrochemical Cells with Semiconductor and Insulator Electrodes

Fast Photocurrent Transients in Photoelectrochemical Cells with Semiconductor and Insulator Electrodes
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具有半导体和绝缘体电极的光电化学电池中的快速光电流瞬变

DOI:
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发表时间:
1984
期刊:
影响因子:
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通讯作者:
F. Decker
F. Decker
中科院分区:
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文献类型:
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作者:
F. Willig;K. Bitterling;K. Charlé;F. Decker

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Photocurrent transients have been measured with better than 1 nanosecond time resolution in photoelectrochemical cells with insulator and semiconductor electrodes. The shape of the transients observed with semiconductor electrodes in the time window of several nanoseconds can be deduced from a simple equivalent circuit. The transient observed in the external circuit consists of two contributions, the first is the time integral and the second is directly proportional to the actual photoresponse. At low light intensity good semiconductor electrodes show only the first contribution. There is no direct influence of charge carrier discharge or of the Helmholtz-layer as such on the fast transient in the nano-second range.