Reactivity of a Ru(III)-hydroxo complex in substrate oxidations in water
Reactivity of a Ru(III)-hydroxo complex in substrate oxidations in water
复制标题
Ru(III)-羟基配合物在水中底物氧化中的反应活性
DOI：
10.1039/c4cc07488b
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发表时间：
2014
影响因子：
4.9
通讯作者：
T. Kojima
中科院分区：
文献类型：
--
作者：
S. Ohzu;T. Ishizuka;H. Kotani;T. Kojima
单核RuIII-OH络合物通过基于通过RuIII-OH络合物和底物之间的氢键合形成加合物的预平衡过程氧化底物如水中的氢醌。反应机理由氢原子转移转变为电子转移，这取决于底物的氧化电位。
A mononuclear RuIII–OH complex oxidizes substrates such as hydroquinones in water through a pre-equilibrium process based on adduct formation by hydrogen bonding between the RuIII–OH complex and the substrates. The reaction mechanism switches from hydrogen atom transfer to electron transfer depending on the oxidation potential of substrates.