Facile synthesis of in situ phosphorus-doped g-C3N4 with enhanced visible light photocatalytic property for NO purification

Facile synthesis of in situ phosphorus-doped g-C3N4 with enhanced visible light photocatalytic property for NO purification
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轻松原位合成具有增强可见光光催化性能的磷掺杂 g-C3N4 用于净化 NO

DOI:
10.1039/c6ra18349b
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发表时间:
2016-09
期刊:
影响因子:
3.9
通讯作者:
Yuxin Zhang
Yuxin Zhang
中科院分区:
化学3区
文献类型:
--
作者:
Wendong Zhang;Jie Zhang;Fan Dong;Yuxin Zhang

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以氯化磷腈三聚体和硫脲为前驱体,通过热共聚路线合成了一种具有典型光学性质的新型磷掺杂g-C3N4。通过 XRD、XPS、TEM、BET-BJH、UV-vis、DRS 和 PL 对样品进行了表征。通过在可见光照射下去除室内空气中的 NO 来评价它们的光催化活性。对其典型的光学性能和增强的光催化活性进行了详细研究。目前的工作可以为光催化材料前体的适当选择提供新的见解。
A novel phosphorus doped g-C3N4 with typical optical property has been synthesized using phosphonitrilic chloride trimer and thiourea as precursors through a thermal copolymerization route. The samples were characterized by XRD, XPS, TEM, BET-BJH, UV-vis, DRS and PL. Their photocatalytic activities were evaluated by the removal of NO at the indoor air level under visible light irradiation. The typical optical performance and enhanced photocatalytic activity have been investigated in detail. The present work could provide new insight into the appropriate selection of the precursor for photocatalytic materials.
通过非金属元素掺杂增强 g-C3N4 光活性的策略:第一性原理研究
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