An Eco-friendly, Convenient, and Practical Conversion of Arylamines to Oxazolidinones
An Eco-friendly, Convenient, and Practical Conversion of Arylamines to Oxazolidinones
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DOI：
10.1246/cl.2009.584
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发表时间：
2009-06-05
影响因子：
1.6
通讯作者：
Xu, Guang-Yi
中科院分区：
文献类型：
--
作者：
Gong, Hang;Yang, Nian-Fa;Xu, Guang-Yi
在1，4-二氮杂双环[2，2，2]辛烷（DABCO）存在下，以碳酸亚乙酯和芳胺为原料，一步合成了恶唑烷酮。在大多数情况下，获得了中等至高的产物收率。该反应可以被认为是二氧化碳固定反应，因为碳酸亚乙酯是通过环氧乙烷与二氧化碳的反应合成的。
A one-step procedure for efficient synthesis of oxazolidinone only using ethylene carbonate and arylamines in the presence of 1,4-diazabicyclo[2,2,2]octane (DABCO) was developed. In most cases, moderate to high yield of products were obtained. This reaction can be considered a carbon dioxide fixation reaction since ethylene carbonate was synthesized via reaction of ethylene oxide with carbon dioxide.