Direct aerobic oxidation of primary alcohols to methyl esters catalyzed by a heterogeneous gold catalyst
Direct aerobic oxidation of primary alcohols to methyl esters catalyzed by a heterogeneous gold catalyst
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DOI：
10.1007/s10562-007-9086-9
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发表时间：
2007-07-01
影响因子：
2.8
通讯作者：
Christensen, Claus H.
中科院分区：
文献类型：
--
作者：
Nielsen, Inger S.;Taarning, Esben;Christensen, Claus H.
在非均相金催化剂上用分子氧氧化伯醇的甲醇溶液可以高产率地制备甲酯。这种新方法的多功能性通过以下事实得到了证明：烷基醇、苄醇和烯丙型醇以及含有胺官能度的醇以良好至优异的产率被氧化。
Methyl esters can be produced in high yields by oxiding methanolic solutions of primary alcohols with dioxygen over a heterogeneous gold catalyst. The versatility of this new methodology is demonstrated by the fact that alkylic, benzylic and allylic alcohols, as well as alcohols containing an amine functionality are oxidized in good to excellent yields.