Concerning the dependence of the volume of activation for a limiting D substitution mechanism on the size of the leaving group. The aquation of pentacyano(amine)ferrate(II) complexes
Concerning the dependence of the volume of activation for a limiting D substitution mechanism on the size of the leaving group. The aquation of pentacyano(amine)ferrate(II) complexes
复制标题
关于限制 D 取代机制的活化体积对离去基团大小的依赖性。
DOI：
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发表时间：
1991
期刊：
影响因子：
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通讯作者：
R. V. Eldik
中科院分区：
文献类型：
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作者：
K. B. Reddy;R. V. Eldik
研究了Fe（CN）5（NH 2 R）3−（R=H，CH 3，C2 H5，i-C3 H7，和CH 2 Ph）型配合物的一系列极限解离取代反应随压力的变化，以研究相关活化体积对离去基团（NH 2 R）大小的依赖性.结果进行了比较，在文献中的其他限制解离取代反应的八面体配合物的数据，并得出了类似的结论。提出了这种观察的可能原因
A series of limiting dissociative substitution reactions of complexes of the type Fe(CN) 5 (NH 2 R) 3− (R=H, CH 3 , C 2 H 5 , i-C 3 H 7 , and CH 2 Ph) were studied as a function of pressure in order to investigate the dependence of the associated volume of activation on the size of the leaving group (NH 2 R). The results are compared to data available in the literature for other limiting dissociative substitution reactions of octahedral complexes, and a similar conclusion is reached. Possible reasons for this observation are presented