Zeolitic imidazolate framework materials: recent progress in synthesis and applications
Zeolitic imidazolate framework materials: recent progress in synthesis and applications
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DOI：
10.1039/c4ta02984d
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发表时间：
2014-10-28
影响因子：
11.9
通讯作者：
Xia, Yongde
中科院分区：
文献类型：
--
作者：
Chen, Binling;Yang, Zhuxian;Xia, Yongde
沸石咪唑盐骨架（ZIF）代表了一类新型特殊的金属有机骨架，由咪唑盐连接基和金属离子组成，其结构与传统的铝硅酸盐沸石相似。其固有的多孔特性、丰富的功能以及卓越的热稳定性和化学稳定性使得各种 ZIF 材料具有广泛的潜在应用。过去 5 年里，这个快速发展的领域出现了爆炸性的研究活动，从 ZIF 的合成方法到有吸引力的应用。在这篇综述中，分析和总结了生成粉末和膜/薄膜 ZIF 材料的不同合成策略的发展和最新进展。讨论和回顾了过去几年它们在气体分离、催化、传感和电子设备以及药物输送方面的有吸引力和潜在的应用。此外，还介绍了ZIF材料的前景和潜在的新发展。
Zeolitic imidazolate frameworks (ZIFs) represent a new and special class of metal organic frameworks comprised of imidazolate linkers and metal ions, with structures similar to conventional aluminosilicate zeolites. Their intrinsic porous characteristics, abundant functionalities as v well as exceptlonal thermal and chemical stabilities have led to a wide range of potential applications for various ZIF materials. Explosive research activities ranging from synthesis approaches to attractive applications of ZIFs have emerged in this rapidly developing field in the past 5 years. In this review, the development and recent progress towards different synthesis strategies to generate both powder and membrane/film-based ZIF materials are analysed and summarised. Their attractive and potential applications in gas separation, catalysis, sensing and electronic devices, and drug delivery in the past years are discussed and reviewed. In addition, the prospects and potential new development of ZIF materials are presented.