Chemoselective Carbon-Carbon Cross-Coupling via Palladium-Catalyzed Copper-Mediated C-S Cleavage of Disulfides
Chemoselective Carbon-Carbon Cross-Coupling via Palladium-Catalyzed Copper-Mediated C-S Cleavage of Disulfides
复制标题
通过钯催化铜介导的二硫化物 C-S 裂解实现化学选择性碳-碳交叉偶联
DOI：
10.1002/adsc.201300776
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发表时间：
2014-02-10
影响因子：
5.4
通讯作者：
Wang, Xi-Cun
中科院分区：
文献类型：
--
作者：
Quan, Zheng-Jun;Lv, Ying;Wang, Xi-Cun
描述了一种有效的碳-碳键形成方法。该方法采用钯催化的铜介导的二杂芳基二硫化物与芳基硼酸或炔的交叉偶联，以通过非反应性CS键裂解来递送CC偶联产物。偶联反应的范围，包括二硫化物和芳基硼酸或炔，被记录。
An efficient method for carbon-carbon bond formation is described. The process employs the palladium-catalyzed copper-mediated cross-coupling of diheteroaryl disulfides with arylboronic acids or alkynes to deliver CC coupling products through unreactive CS bond cleavage. The scope of the coupling reactions, including both the disulfides and arylboronic acids or alkynes, are documented.