Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines.
Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines.
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DOI：
10.1039/c1cc12263k
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发表时间：
2011-06
影响因子：
4.9
通讯作者：
K. Gao;Chang-Bin Yu;Wei Li;Yong‐Gui Zhou;Xumu Zhang
中科院分区：
文献类型：
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作者：
K. Gao;Chang-Bin Yu;Wei Li;Yong‐Gui Zhou;Xumu Zhang
Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl](2)/(S)-Xyl-C(3)*-TunePhos complex as the catalyst in the presence of morpholine-HCl.
