Highly Efficient Hydrosilylation of Diyne and Triyne π-Electron Bridges: Its Application to Fluorescent Dyes and Silylene-Spaced Vinylarene Compounds
Highly Efficient Hydrosilylation of Diyne and Triyne π-Electron Bridges: Its Application to Fluorescent Dyes and Silylene-Spaced Vinylarene Compounds
复制标题
二炔和三炔π电子桥的高效硅氢加成：其在荧光染料和硅基间隔乙烯基芳烃化合物中的应用
DOI：
10.1021/om049878f
复制
发表时间：
2004
期刊：
影响因子：
--
通讯作者：
J. Ko
中科院分区：
文献类型：
--
作者：
Taegweon Lee;I. Jung;K. Song;Chul Baik;Sanghoon Kim;Duckhyun Kim;S. Kang;J. Ko
多种二炔和三炔π电子桥被氢化硅烷化以提供双和三(甲硅烷基乙烯基)π电子桥。氢化硅烷化产物与多种含有发色团单元的化合物发生取代反应，得到荧光染料取代产物。甲硅烷基氢化物易于获得，可用于构建大量的共聚物。
A variety of diyne and triyne π-electron bridges were hydrosilylated to afford the bis- and tris(silylvinyl) π-electron bridges. The hydrosilylation products underwent substitution reactions with a variety of compounds containing chromophore units to give fluorescent dye substituted products. The easy access of the silyl hydrides may be applied to construct a large number of copolymers.